Will drinking a sugared drink like Gatorade® help with a 1-hour workout?

Yes, a moderately high amount of sugar can do it, but it may depend on the type of exercise.  A product like Gatorade® provides hydration,

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Is there a study saying vitamin D can give me a better VO2 max?

Maybe.  VO2 max measures the maximum amount of oxygen someone can use during exertion. This gives an indication of aerobic fitness, though it does not

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